Not counting Ophis, Primordial Beings, Trihexa and Great Red

#1: Shiva
#2: Vishnu
#3: Brahma
#4: Zeus
#5: Palutena
#6: Odin
#7: Posiedon/Hades
#8: Thor
#9: Ra
#10: Amaterasu

#85: Crimson

#99993: Issei

#618: Vali

#1271: Mirajane

#1284: Yang/Leone

#1001: Seras

#45: Alucard

#74: The 4 Seraphs

#80: Sirzechs

#79: Grayfia

#81: Serafall

#90: Ajuka

#76: Azaezal

#79: Katerea Leviathan

#821: Scacath

#500: Gilgamesh (reincarnate)

#23: Ddraig/Albion

#20: Helios (3rd heavenly dragon)

#53: Tiamat

#65: Vitra

#58: Fafnir

#4173: Rias

#4172: Akeno

#5825: Kiba

#4262: Koneko