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Summary:

Doctor Octopus hacks into Iron Man's armours and sends one to kill Norman Osborn. While Norman blames Iron Man for the attack and threatens legal action, Spider-Man recovers a tentacle from an Octo-Bot and learns more about Doctor Octopus' history with both Oscorp and Norman himself. Doctor Octopus then attacks the Helicarrier in an arc reactor-powered suit of armour and abducts Norman and Harry, so Spider-Man dons the Iron Spider suit to save them.

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Peter and Harry have games night at the Osborn penthouse, as his father had to work late and could not take them to a baseball game. Peter's spider-sense goes off and there is an explosion coming from Normans office, when they rushed to check Peter gets trapped downstairs, telling Harry he will go for help, giving him time to change into Spider-Man. When Harry entered his fathers office he finds him being attacked by Iron Man. Spider-Man arrives and tries to stop Iron Man who is non-responsive. He then tried to shoot him with missiles, but doges them all. In the distraction Norman grabs a experimental machine gun and fires at Iron Man. During then he uses a electro-glove to disrupt the armor allowing Spider-Man to punch him knocking his head off much to Spider-Man horror. The armor is revealed to be empty, so he travels to Stark Industries to find out what happened. When he arrives he finds Iron Man battling his own armors, working with Spider-Man he takes them all out. They discover an Octobot hacking his system, which they try to follow but escapes through a vent. The Ocotobot returns to Doc Ock who uses the Arc Reactor technology to build his own armor. The Osborn are taken to the Helicarrier for protection, where they are called into Doc Connors lab to view his regarding a piece of the tentacle. Doc Connors explained that it was created by Dr. Otto Octavius. Osborn reveals the Octavius was a former employee that died in accident. Doc Ock reactivate's the tentacle and attack Osborn, but it is destroyed by Iron Man. Doc Ock in his Iron Octopus armor arrives and kidnaps both the Osborns. He takes them both to his secret lab and threatens Osborn. Spider-Man arrives in his Iron Spider armor and rescues his friends. He then battled the Iron Octopus, but before he could defeat Spider-Man, Iron Man arrives and blast Doc Ock and is defeated due to his faulty Arc Reactor. Norman recovers Doc Ock's body and provides him the medical treatment he needs with plans to use him again in the future. Iron Man thanks Spider-Man and agrees to another possible team up in the future.