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Summary:

Doctor Octopus captures Spider-Man and takes more blood samples for his experiments. Norman Osborn reveals himself to be the true mastermind behind all of Doctor Octopus' schemes, and he plans to create an unstoppable army from Spider-Man's DNA. Doctor Octopus is angry at Norman for treating him unfairly, so he takes revenge by injecting him with a mixture of DNA from both Spider-Man and Venom, mutating him into a green-skinned monster.

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Peter and Harry celebrate on a night out in Manhattan for doing well in school, with Harry's dad taken them out for dinner. But before they can enter the restaurant Peter is called away on a mission by Power Man and Norman is contacted by Doctor Octopus, leaving Harry alone with his credit card. Spider-Man finds the team battling the Frightful Four in a Oscorp warehouse. The fight is revealed to be a trap and they are attacked by a horde of Octobots. They destroy all the Octobots, but Spider-Man goes missing. He is knocked out and taken to Doctor Octopus' secret lab. The team contact Nick Fury, but a small robot broke free from one of the Octobots and the team decide to follow it. Doc Ock extracts a DNA sample from Spider-Man revealing the true origin of the Venom Symbiote and that he is the key to combining human and animal DNA. Spider-Man however broke free and battled one of the Octobots, destroying Doctor Octopus' life support system, but he was however electrically shocked by a gauntlet worn by Norman Osborn. Norman reveals that he is the one behind the attacks and he is the employer of Doctor Octopus. He then tries to remove his mask but Doctor Octopus injects Norman with a genetic sample. The team continued to follow the robot but it moved slow so Nova zapped it causing it to overload and move at increased speed. Norman transforms into a green goblin like creature, while Spider-Man is still trapped. Doctor Octopus reveals that the origin of Spider-Man was down to a genetically enhanced spider created at Oscorp. The team arrive and battle Dock Ock just in time for Osborn transformation to complete. The Goblin creature however breaks Doc Ock's control and attacks him, tearing his suit apart. The team tried to escape through a tunnel but the are electrocuted by the Goblin, they try to fight the creature but he knock them all out but Spider-Man who holds him at bay trying to reach Norman inside. Spider-Man then use the gauntlet against him sending flying above into the Oscorp building. The places caught fire, but S.H.I.E.L.D. arrive to help but the Goblin gets away. The team recovered in the infirmary as Nick Fury spoke with Spider-Man, who decides to go after the Goblin alone.