Let's go through some basic knowledge before I talk about it further...

Characters: Ash Ketchum & James
Canonical?: Fanon
Relationship status: Enemies
Also known as: SatoKoji, KojiSato

What do I think?:

Once again, no
Just look at the age difference, that's all I really have to say!!!

I shall rate this ship: -1000/10

Thanks for reading, see you in the next chapter!!!