Ash Ketchum

Pokémon
Pikachu
Inteleon
Orbeettle
Dracozolt
Coalossal
Zacian
Charizard(Mega x)
Sceptile
Garchomp
Greninja(Synchro-evolution)
Lycnaroc(Dusk form)
Melmetal

Paul Shinji

Pokémon
Corviknight
Falinks
Centiskorch
Grimmsnarl
Toxtricity
Zamazenta
Electrivire
Aggron(Mega)
Ursaring
Honchkrow
Drapion
Tyranthrum
(He caught it when he went to Kalos)