First chair
"Darling"

Personality: a remarkably well adjusted supervillain. Darling is in it for the money and honestly not a whole lot else.
Power: beloved fiction
Explanation of power: the user can falsify emotions in another person just by touching them. These memories will wear off after 24 hours.
Crimes: larceny

Second and third chair
Twin terrors of the strike team
"Matchlock" and "clover"

Personality: a duo of criminals who have been working together for as long as they've been criminals. Clover is energetic and chatty while matchlock is cold and sarcastic.
Powers: magic bullet and lucky charm
Explanation of power (magic bullet): the user can change the trajectory of any bullet fired from a gun they are in direct contact with.
Explanation of power (lucky charm): the user can imbue any object they touch with good or bad luck. The enchantment last 24 hours.
Crimes: murder, larceny, vandalism, assault

Fourth chair
Head of the counter-intelligence division
"Dismount"

Personality: an incredibly laid-back supervillain with a pretty large lazy streak. It's unclear why he's the leader of the counter-intelligence division as he doesn't have a power or personality that would lead him to success in that field.
Power: wave rider.
Explanation of power: the user can summon waves of water at will.
Crimes: larceny, murder

Fifth chair
Head of the assassination division
"Pyrrhic"

Personality: a jaded girl who enjoys putting heroes in their place.
Power: pain split
Explanation of power: any wound she receives is reflected back onto the one who inflicted it so that they share an injury.