This is season 1...
I'll write the next part soon...

Aries ♈= Bought a pin for Gemini and asked to be her Valentine.

Episode 10 "Dark Cupid"

Taurus♉= Got locked in a cage with Libra.

Episode 16 "Animan"

Gemini ♊=mmm....it's complicated.

Cancer ♋: Went on a limosine ride with Prince Ali.

Episode 23 " Princess Fragrance"

Leo♌= Gave Libra an umbrella while he was getting soaking wet.

Episode 25 Origins part 2 "Stoneheart"

Virgo♍= mmm...it's complicated.

Libra♎= Responded to a love letter from Leo.

Episode 15 "Dark Cupid"

Scorpio♏= Wrote a love song for Pisces.

Episode 24 Origins part 1"Stoneheart"

Sagittarius♐= nothing... yet.

Capricorn♑=nothing that we know of..

Aquarius♒=Asked Libra on a date.

Episode 8 "Evillustrator"

Pisces♓= Kissed their crush on the final scene of the school play.

Episode 11"Horrificator"

Note: the order varies, there's a different one from google, fandom wiki, netflix; so if you want to watch the episodes again then just search them by their name.

_andrea✌