The Family

The Matriarch
Lily Collins as Mary Rogers-Barnes

The Daughter
Mackenzie Foy as Becca Barnes

The Patriarch
Sebastian Stan as James Buchanan "Bucky" Barnes

The Brother
Chris Evans as Steve Rogers/Captain America

The Son
Robert Downey Jr. as Tony Stark/Iron Man

Team Cap

Anthony Mackie as Sam Wilson/Falcon

Elizabeth Olsen as Wanda Maximoff/Scarlet Witch

Paul Rudd as Scott Lang/Ant-Man

Jeremy Renner as Clint Barton/Hawkeye

Team Iron Man

Tom Holland as Peter Parker/Spider Man

Scarlett Johansson as Natasha Romanoff/Black Widow

Paul Bettany as Vision

Don Cheadle as James "Rhodey" Rhodes/War Machine

Introducing

Chadwick Boseman as T'Challa Udaku/Black Panther

And

Daniel Bruhl as Baron Zemo

With

Emily VanCamp as Sharon Carter
Martin Freeman as Everett Ross
William Hurt as Thunderbolt Ross
Frank Grillo as Crossbones
Marisa Tomei as May Parker
John Slattery as Howard Stark
Hope Davis as Maria Stark
John Kani as King T'Chacka